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Biodegradable, superhydrophobic walnut wood membrane for the separation of oil/water mixtures

《化学科学与工程前沿（英文）》 2022年 第16卷 第9期   页码 1377-1386 doi: 10.1007/s11705-022-2157-z

摘要： The preparation of environmentally friendly oil/water separation materials remains a great challenge. Freeze-drying of wood after lignin removal yields wood aerogels, which can be used as substrates to prepare fluorine-free environmentally friendly superhydrophobic materials, However, they are more suitable for absorption rather than filtration applications due to their poor strength. A study using cross-sections of pristine wood chips as substrates retains the original strength of wood, but the use of the cross-sectional of wood pieces limits their thickness, strength, and size. In this paper, a degradable fluorine-free superhydrophobic film (max. water contact angle of approximately 164.2°) with self-cleaning and abrasion resistance characteristics was prepared by a one-step method using pristine and activated walnut longitudinal section films as the substrate, with tetraethyl orthosilicate as a precursor and dodecyltriethoxysilane as a modifier. The tensile strength results show that superhydrophobic films with pristine or activated wood substrates maintained the strength of pristine wood and were 2.2 times stronger than the wood aerogel substrate. In addition, after cross-laminating the two samples, the films had the ability to separate oil and water by continuous filtration with high efficiency (98.5%) and flux (approximately 1.3 × 103 L∙m‒2∙h‒1). The method has potential for the large-scale fabrication of degradable superhydrophobic filtration separation membranes.

关键词： wood nanotechnology     superhydrophobic     biodegradable     surface modification     oil/water separation    

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Cultivars and oil extraction techniques affect Cd/Pb contents and health risks in oil of rapeseed grown

《环境科学与工程前沿（英文）》 2023年 第17卷 第7期 doi: 10.1007/s11783-023-1687-z

摘要：

● Organic solvent extracted fewer Cd/Pb in rapeseed oil than physical pressing.

关键词： Rapeseed oil     Oil extraction technologies     Human health risk assessment     Cd/Pb-contaminated farmland     Substitute planting    

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Co-hydrotreating light cycle oil-canola oil blends

Huali WANG, Hena FAROOQI, Jinwen CHEN

《化学科学与工程前沿（英文）》 2015年 第9卷 第1期   页码 64-76 doi: 10.1007/s11705-015-1504-8

摘要： Canola oil and light cycle oil (LCO) blends were co-hydrotreated over a commercial hydrotreating catalyst (NiMo/Al O ) to produce diesel fuel with a green diesel component. High hydrodeoxygenation, hydrodesulphurization and hydrodenitrogenation catalytic activities were achieved for all three feedstocks tested in the temperature range of 350–380 °C with a hydrogen pressure of 7 MPa and a gas/oil ratio of 800 nL/L. The hydrocracking conversion of the 360 °C+ materials in the feedstocks increased by 5% and 15% when 5 and 7.5 wt-% canola oil was added to the LCO, respectively. Compared to the pure LCO, the cetane index of the diesel product formed from hydrotreating the two canola oil-LCO blends increased by 2.5 and 4, respectively. Due to the higher hydrogen requirement to crack and deoxygenate the triglycerides contained in the canola oil, a higher hydrogen consumption was needed to hydrotreat the canola oil-LCO blends.

关键词： hydrotreating     co-hydrotreating     co-processing     canola oil     light cycle oil (LCO)    

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Influence of different oil feed rate on bituminous coal ignition in a full-scale tiny-oil ignition burner

Chunlong LIU, Qunyi ZHU, Zhengqi LI, Qiudong ZONG, Xiang ZHANG, Zhichao CHEN

《能源前沿（英文）》 2013年 第7卷 第3期   页码 406-412 doi: 10.1007/s11708-013-0266-6

摘要： To reduce oil consumption during firing-up and partial-load operation, a tiny-oil ignition burner has been recommended. Through reacting-flow experiments performed on a full-scale experimental setup, the influence of different oil flow rates on bituminous coal combustion as well as flow rates without coal feed was analyzed. The ignition burner is identical to that normally used in an 800 MWe utility boiler. Under operating conditions with flow rates of 50, 100, and 150 kg/h, gas temperature distributions were measured in the burner. At the equivalent measuring points at the exits of the first and second combustion chambers, these distributions remained almost unchanged under a constant coal feed rate of 4 t/h. However on the burner centerline, distributions increased slightly with increasing flow rate. Different gas concentrations were measured at the center of the burner exit. For instance, the O concentration at the burner exit varied from 0.01% to 0.31% whereas CO concentrations were more than 10000 ppm. At the same coal feed rate of 4 t/h, burner resistances are 480, 600, and 740 Pa for oil flow rates of 50, 100, and 150 kg/h, respectively.

关键词： ignition     coal     burner     boiler     oil flow rate    

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世界油气上游国际合作的形势和机会

童晓光

《中国工程科学》 2011年 第13卷 第4期   页码 15-19

摘要：

指出中国利用国外油气的必要性，重点分析了伊拉克、伊朗、巴西、加拿大、委内瑞拉和北美油气上游合作的机会及世界油气国际合作的合同变化趋势，提出了当前扩大油气上游国际合作的主要方向。

关键词： 油气上游国际合作     伊拉克     深水油气勘探     重油和油砂     非常规天然气    

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创新石油与战略思考

康玉柱

《中国工程科学》 2012年 第14卷 第3期   页码 37-40

摘要：

中国油气勘探开发的历史，就是开拓创新的历史。这段历史取得了辉煌的成就，实现了陆相和海相油气勘探两大跨越。自主创新了八大油气地质理论和八大技术系列，发现500多个油气田，2010年产油达2.1×108 t油当量，天然气950×108 m3。从近期研究和实践认为，中国油气资源十分丰富，勘探潜力巨大，勘探领域广泛，并提出了油气资源开发的战略。

关键词： 油气田油气资源     油气资源潜力     油气勘探战略    

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Mesoporous zeolites as efficient catalysts for oil refining and natural gas conversion

Jie ZHU, Xiangju MENG, Fengshou XIAO

《化学科学与工程前沿（英文）》 2013年 第7卷 第2期   页码 233-248 doi: 10.1007/s11705-013-1329-2

摘要： Zeolites have been regarded as one of the most important catalysts in petrochemical industry due to their excellent catalytic performance. However, the sole micropores in zeolites severely limit their applications in oil refining and natural gas conversion. To solve the problem, mesoporous zeolites have been prepared by introducing mesopores into the zeolite crystals in recent years, and thus have the advantages of both mesostructured materials (fast diffusion and accessible for bulky molecules) and microporous zeolite crystals (strong acidity and high hydrothermal stability). In this review, after giving a brief introduction to preparation, structure, and characterization of mesoporous zeolites, we systematically summarize catalytic applications of these mesoporous zeolites as efficient catalysts in oil refining and natural gas conversion including catalytic cracking of heavy oil, alkylation, isomerization, hydrogenation, hydrodesulfurization, methane dehydroaromatization, methanol dehydration to dimethyl ether, methanol to olefins, and methanol to hydrocarbons.

关键词： mesoporous zeolite     catalysis     oil refining     natural gas conversion    

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properties of a silver particle-coated and 1-dodecanethiol-modified superhydrophobic melamine sponge for oil

《化学科学与工程前沿（英文）》 2022年 第16卷 第8期   页码 1237-1246 doi: 10.1007/s11705-022-2140-8

摘要： A Ag particle-coated and 1-dodecanethiol-modified melamine sponge (Ag-DDT-MS) was prepared through surface roughness by coating silver particles and subsequent grafting of a hydrophobic long hydrocarbon chain. Superhydrophobic and 3D porous Ag-DDT-MS was characterized by Fourier transform infrared spectroscopy, scanning electron microscope, energy-dispersive X-ray spectroscopy, and X-ray diffraction. The water contact angle of Ag-DDT-MS reached 159.2°. Ag-DDT-MS exhibited excellent absorption capacity for high viscous oils and organic solvents, ranging from 42.8 to 105.2 g∙g−1. The absorbed oils can be easily collected by the mechanical pressing process, and the oil recovery rate was satisfactory, more than 90% after 20 recycles. Ag-DDT-MS material also demonstrated good stability and excellent compression-recovery ability, keeping 88.6% of the initial height after ten compression-release cycles.

关键词： melamine sponge     oil-absorbing material     hydrophobic     oil-water separation     oil absorption capacity    

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New Challenges, New Opportunities and New Measures for Oil and Gas Cooperation in the Belt and Road

Yu-pu Wang,He Liu

《工程管理前沿（英文）》 2016年 第3卷 第4期   页码 301-313 doi: 10.15302/J-FEM-2016055

摘要： First-mover advantage and solid foundation of oil and gas cooperation is very important to the Belt and Road Initiative. Deeply studied opportunities and challenges of oil and gas cooperation have far-reaching significance to the cooperation in other industries in the Belt and Road. In this article, based on the systematic analysis of the oil and gas supply security, investment environment, regional win-win situation in oil and gas cooperation, new opportunities and challenges about upstream, pipeline, refining, trade, warehousing, engineering technology and equipment are studied. Enhancing capacities in four areas and implementing the 16 measures are given for deepening oil and gas cooperation in the future. Meanwhile, this article also gives suggestions and cooperation directions for countries and companies.

关键词： the Belt and Road     oil & gas cooperation     new challenges     new opportunities     new measures    

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Production of renewable fuels by blending bio-oil with alcohols and upgrading under supercritical conditions

Sainab Omar, Suzanne Alsamaq, Yang Yang, Jiawei Wang

《化学科学与工程前沿（英文）》 2019年 第13卷 第4期   页码 702-717 doi: 10.1007/s11705-019-1861-9

摘要： The work studied a non-catalytic upgrading of fast pyrolysis bio-oil by blending under supercritical conditions using methanol, ethanol and isopropanol as solvent and hydrogen donor. Characterisation of the bio-oil and the upgraded bio-oils was carried out including moisture content, elemental content, pH, heating value, gas chromatography-mass spectrometry (GCMS), Fourier transform infrared radiation, C nuclear magnetic resonance spectroscopy, and thermogravimetric analysis to evaluate the effects of blending and supercritical reactions. The GCMS analysis indicated that the supercritical methanol reaction removed the acids in the bio-oil consequently the pH increased from 2.39 in the crude bio-oil to 4.04 after the supercritical methanol reaction. The ester contents increased by 87.49% after the supercritical methanol reaction indicating ester formation could be the major deacidification mechanism for reducing the acidity of the bio-oil and improving its pH value. Simply blending crude bio-oil with isopropanol was effective in increasing the C and H content, reducing the O content and increasing the heating value to 27.55 from 17.51 MJ·kg in the crude bio-oil. After the supercritical isopropanol reaction, the heating value of the liquid product slightly further increased to 28.85 MJ·kg .

关键词： bio-oil     blending     supercritical     upgrading     characterisation    

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Kinetic study of hydrodesulfurization of coker gas oil in a slurry reactor

Haiding XIANG, Tiefeng WANG

《化学科学与工程前沿（英文）》 2013年 第7卷 第2期   页码 139-144 doi: 10.1007/s11705-013-1323-8

摘要： Coker gas oil (CGO) is a poor-quality feedstock for fluidized bed catalytic cracking (FCC) or hydrocracking. The pretreatment of CGO, especially hydrotreating, can significantly improve the product quality and protect the catalyst. In this work, we studied the hydrodesulfurization (HDS) of CGO in a slurry reactor. All the experiments were carried out in an autoclave using a NiMo/Al O catalyst at reaction temperature 340°C–400°C, pressure 6–10 MPa, and stirring speed 800 r·min , with hydrogen-to-oil ratio in the range of 500–1500. The effects of the operating parameters on the desulfurization ratio were investigated and discussed. A macro reaction kinetic model was established for the HDS of CGO in the slurry reactor.

关键词： coker gas oil     hydrodesulfurization     slurry reactor     reaction kinetic model    

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Highly hydrophobic oil−water separation membrane: reutilization of waste reverse osmosis membrane

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1606-1615 doi: 10.1007/s11705-022-2200-0

摘要： The increasing applications of seawater desalination technology have led to the wide usage of polyamide reverse osmosis membranes, resulting in a large number of wasted reverse osmosis membranes. In this work, the base nonwoven layer of the wasted reverse osmosis membrane was successfully modified into the hydrophobic membrane via surface deposition strategy including TiO2 and 1H,1H,2H,2H-perfluorooctyltrichlorosilane (PFOTS), respectively. Various techniques were applied to characterize the obtained membranes, which were then used to separate the oil–water system. The optimally modified membrane displayed good hydrophobicity with a contact angle of 135.2° ± 0.3°, and its oil–water separation performance was as high as 97.8%. After 20 recycle tests, the oil–water separation performance remained more than 96%, which was attributed to the film adhesion of the anchored TiO2 and PFOTS layer on the surface. This work might provide a new avenue for recycling the wasted reverse osmosis membrane used in oily wastewater purification.

关键词： oil–water separation     wasted reverse osmosis membrane     hydrophobic modification    

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全球主要盆地油气分布规律

康玉柱

《中国工程科学》 2014年 第16卷 第8期   页码 14-25

摘要：

全球发育的含油气盆地有上千个，根据盆地结构特征可将含油气盆地分为3 大类型：克拉通盆地、断陷盆地和前陆盆地。笔者按这3 大类型盆地论述其油气分布规律。克拉通盆地：油汽主要分布在盆地内的古隆起、古斜坡，区域性的不整合及断裂带内；断陷盆地：油气主要分布在深凹带内的构造带、陡坡带和缓坡带；前陆盆地：油气主要分布在前陆断摺带、斜坡带、逆埯带及坳陷帶。这些规律性的认识，对全球油气勘探工作具有重要的指导意义。

关键词： 含油气盆地     油气田     油气分布规律    

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EXTRACTION AND EVALUATION OF EDIBLE OIL FROM SCHIZOCHYTRIUM SP. USING AN AQUEOUS ENZYMATIC METHOD

《农业科学与工程前沿（英文）》 2021年 第8卷 第4期   页码 623-634 doi: 10.15302/J-FASE -2021400

摘要：

Schizochytrium sp., a marine microalga, is a potential source of edible oil due to its short growth cycle and rapid lipid accumulation, especially of docosahexaenoic acid. An approach to isolate edible microalgal oil from Schizochytrium sp. using aqueous enzymatic extraction (AEE) was developed. Parameters were optimized by single-factor experiments followed by Box-Behnken design. Proteases were effective in extracting oil. The maximum free oil recovery (49.7%±0.58%) and total oil recovery (68.1%±0.94%) were obtained under optimum conditions of liquid-to-solid ratio of 4.8:1, a 2.5% enzyme concentration of papain and an extraction time of 2.2 h. There was a significant difference (P<0.05) in polyunsaturated fatty acid composition between microalgal oil obtained by AEE and by Soxhlet extraction, with the former having superior physiochemical properties and higher concentrations of bioactive components including total phenolic compounds and total tocopherols. These findings indicate a potential application of AEE for extraction of oil from Schizochytrium sp.

 

关键词： antioxidant activity / aqueous enzymatic extraction / edible microalgal oil / fatty acid composition / physicochemical properties    

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Influence of boundary conditions and turntable speeds on the stability of hydrostatic oil cavity

Zhaomiao LIU, Chengyin ZHANG, Feng SHEN

《机械工程前沿（英文）》 2011年 第6卷 第3期   页码 359-368 doi: 10.1007/s11465-011-0222-2

摘要：

The flow, bearing, and carrying capacity of the cycloidal hydrostatic oil cavity in hydrostatic turntable systems are numerically simulated, considering the rotation speeds of a turntable from 0 to 5 m/s and different boundary conditions. The vortex effect is weakened, and the stability of the oil cavity is enhanced with the increase in lubricant viscosity. However, the increase in inlet speed, depth, and inlet radius of the oil cavity causes the vortex effect to increase and the stability of oil cavity to reduce. With the increase in the oil film thickness, the carrying capacity of the oil cavity diminishes. The oil cavity pressure increases along the direction of the motion of the turntable; it is distributed unevenly because of the rotation of the turntable. With the increase in turntable speed, the location and size of the vortex scope in the oil cavity flow field and the strength of the vortex near the entrance gradually weaken and move away from the entry. The distribution of pressure is determined by the locations of the vortex. When the vortex is close to the wall, the wall pressure increases at its location. Otherwise, the wall pressure decreases first and then increases after the center of the vortex.

关键词： hydrostatic oil cavity     flow state     oil cavity pressure     stability     vortex    

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标题 作者 时间 类型 操作

Biodegradable, superhydrophobic walnut wood membrane for the separation of oil/water mixtures

期刊论文

Cultivars and oil extraction techniques affect Cd/Pb contents and health risks in oil of rapeseed grown

期刊论文

Co-hydrotreating light cycle oil-canola oil blends

Huali WANG, Hena FAROOQI, Jinwen CHEN

期刊论文

Influence of different oil feed rate on bituminous coal ignition in a full-scale tiny-oil ignition burner

Chunlong LIU, Qunyi ZHU, Zhengqi LI, Qiudong ZONG, Xiang ZHANG, Zhichao CHEN

期刊论文

世界油气上游国际合作的形势和机会

童晓光

期刊论文

创新石油与战略思考

康玉柱

期刊论文

Mesoporous zeolites as efficient catalysts for oil refining and natural gas conversion

Jie ZHU, Xiangju MENG, Fengshou XIAO

期刊论文

properties of a silver particle-coated and 1-dodecanethiol-modified superhydrophobic melamine sponge for oil

期刊论文

New Challenges, New Opportunities and New Measures for Oil and Gas Cooperation in the Belt and Road

Yu-pu Wang,He Liu

期刊论文

Production of renewable fuels by blending bio-oil with alcohols and upgrading under supercritical conditions

Sainab Omar, Suzanne Alsamaq, Yang Yang, Jiawei Wang

期刊论文

Kinetic study of hydrodesulfurization of coker gas oil in a slurry reactor

Haiding XIANG, Tiefeng WANG

期刊论文

Highly hydrophobic oil−water separation membrane: reutilization of waste reverse osmosis membrane

期刊论文

全球主要盆地油气分布规律

康玉柱

期刊论文

EXTRACTION AND EVALUATION OF EDIBLE OIL FROM SCHIZOCHYTRIUM SP. USING AN AQUEOUS ENZYMATIC METHOD

期刊论文

Influence of boundary conditions and turntable speeds on the stability of hydrostatic oil cavity

Zhaomiao LIU, Chengyin ZHANG, Feng SHEN

期刊论文